Is there a website where people can post stuff that they want.?

And if you have something that they want, you can sell it to them.

Is there any website like that?

Plus how can you get started on ebay?

Answer:
eBay actually has a section that describes what you are saying -- their Want it Now page http://pages.ebay.com/wantitnow/index.ht. where those who want to buy something post the stuff they want to buy and sellers look for them. Sellers can simply look for them and offer them the items they have

Your first stop should be eBay's Guide to Seller Services http://pages.ebay.com/help/sell/services.

eBay's Seller Central has all the resources you need to learn about the basics of selling on eBay http://pages.ebay.com/sellercentral/inde.
try www.craigslist.com too
That page on eBay is a great help.

Also, eBay does have a "Want it Now" section that buyers can specify something they want, and sellers can browse through it.
craigslist.com

there are tutorials on ebay that explain how to get started. Also books, one is ebay for dummies
Try: http://freecycle.org/
Craigslist is good only for locals, ebay have a wider reach

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